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Changes Are Coming to Hazard Communication

The new GHS hazard communication recommendations will impact manufacturers, distributors, and users of welding consumables Article prepared by the AWS Safety and Health Committee. Comments can be submitted to SHC Secretary Steve Hedrick (steveh@aws.org). Reprinted with permission: The Welding Journal  This article discusses the basic provisions of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Hazard Communication System, how they differ from previous hazard communication requirements, and with a focus on the classification process, their likely impact upon the welding workplace. In July 2003, the GHS was endorsed by the United Nations (UN) Economic and Social Council. The GHS was drafted to address the need for a common framework for the technical classification and communication of chemical hazards. According to the UN, “It (GHS) aims at providing a basis for harmonization of rules and regulations on chemicals at a national, regional, and worldwide level, an important factor also for trade facilitation.” The GHS objective is to provide a universal systematic, empirical approach for physical, health, and environmental hazard classification of pure substances and mixtures. The hazard classification process is the foundation upon which this systematic prescriptive approach is built. Once a product’s hazards have been classified, these chemical property, regulatory or test data derived classifications then drive much of the required outputs on product Safety Data Sheets (SDS) and package/container warning labels. The GHS is not a regulation or a standard, but a set of international recommendations that a competent authority can adopt, in whole or in part, according to the “building-block” approach. The UN publishes the GHS guidelines on hazard classification criteria, standardized label elements, and SDS format in its publication known as the ‘Purple Book.’ The first edition of the Purple Book was approved by the Committee of Experts at its first session in December 2002. The GHS Purple Book is updated and revised every two years. The U.S. Adoption of GHS In March 2012, the United States Occupational Safety and Health Administration (OSHA) adopted the third revised edition of the GHS into its Revised Hazard Communication Standard. A majority of the new OSHA requirements take effect in June 2015, which corresponds to the European Union’s final deadline for incorporation of the GHS requirements for mixtures, following their previous adoption for pure substances. Many countries worldwide have similarly adopted GHS into their regulatory framework, or have plans to do so. The Key Principle of GHS Is Classification of Hazards Under GHS guidelines, hazard classification is specifically derived based on the intrinsic properties of a chemical substance or mixture. In other words, it is based upon the hazards the chemical substance or mixture exhibits in the form in which it is purchased, shipped, and received in commerce. This hazard classification does not include risks arising from subsequent use or transformation in the workplace. However, successful hazard communication includes information on the presence of potential end-use risks as well as the intrinsic hazards. Therefore, hazard communication information is still required in appropriate sections of a GHS formatted SDS or label to alert the user to minimize exposures and risks. Accordingly, by following established classification criteria under GHS, solid form welding consumable electrodes should be considered “Not classified as hazardous according to GHS,” due to their lack of intrinsic hazards. By definition, they are not considered exempt articles though, because they can present safety and health risks during their actual use in the workplace. For this reason, while they may not require the GHS label elements on product labeling, full GHS 16 Section formatted Safety Data Sheets are required for complete and proper hazard communication to end users of these products. Of course, packaging should continue to provide applicable warnings for physical hazards and health risks generated during the use of welding electrodes. Granular form welding products such as submerged arc flux are classified under GHS as they may present intrinsic hazards in the form they are sold, shipped, and received by the customer. They can become airborne as a dust, and the dust may contain hazardous constituents such as crystalline silica. Once properly classified according to GHS guidelines, they must have applicable compliant GHS labels on packaging as well as Safety Data Sheets authored and provided in accordance with competent authority requirements. The GHS Compliance Timeline In the United States, OSHA requires that all manufacturer/supplier’s SDS and product labeling conform to the GHS (Purple Book, Revision 3) requirements as of June 1, 2015. Distributors have until December 1, 2015, to ensure that all products sold conform to the new requirements. Canada has stated its intention to adopt GHS in alignment with the United States, but has yet to announce a date as to when GHS will be formally adopted into its existing WHMIS requirements. The European Union’s (EU) final implementation compliance date for SDS and label conformance coincides with OSHA’s June 2015 deadline. However, in the EU, there is still additional time allowed for distributors. China adopted GHS Purple Book, Revision 4 labeling and SDS requirements officially on May 1, 2011. How GHS Hazard Communication Is Different It’s true that data sheets and container/package warning labels have been around a good while as mandated by OSHA in the United States. Canada’s WHMIS includes similar hazard communication statutes, and so have most developed countries around the globe. The difference is that these pre-existing requirements were, by and large, performance based — whereas the new GHS requirements are principally prescriptive. In other words, before, it was up to the manufacturer to figure out what the hazards of their products were and to then develop Material Safety Data Sheets and container labels with whatever content they deemed necessary in order to adequately warn potential users in the workplace regarding their hazards and safe use of the products. Under GHS, manufacturers must first classify their products, be they considered substances or mixtures, according to their physical, health, and environmental hazards. (In the United States, OSHA does not specifically require provision of the environmental risk information as it doesn’t have jurisdiction over environmental matters.) This classification process follows according to specific empirically based criteria, and then from those prescribed classifications mandatory label and SDS text, warning statements, and warning symbol outputs are derived. Many of these classification guidelines rely on regional regulations, best practice standards, scientific chemical property data, published toxicological or ecological test data, and related published research studies. Therefore, manufacturers must obtain and compile this applicable published information by doing an extensive review of the literature, by subscribing to a service that provides this information, and/or by conducting their own scientific testing and research. In most cases, testing is not a requirement, as GHS established “Bridging Principles” that allow classification and hazard ratings to be calculated for mixtures based on the data available for its base level elemental or compound components. Figure 1 provides an example of how a label might look before and after GHS.
Hazard Communicaiton - Fig 1

Figure 1

                In the EU, some compounds have what is known as a Harmonized Classification. Basically, a technical risk assessment committee completed reviews of many high priority materials and established a classification that is mandatory in the EU. This information and other types of information related to chemical information associated with GHS and other requirements can be found on the European Chemicals Agency (ECHA) website. GHS Is Not Quite Harmonious While the GHS charter includes the goal of providing a harmonized process for hazard communication across the globe, in practice this is not necessarily how things have turned out. Because GHS offers a building block approach for voluntary adoption by countries into their regulatory framework, there are sometimes significant regional and country-specific differences in the classification rules and other implementation of the system which, in turn, affect required SDS and label outputs. A major challenge for business is that many countries or regions are adopting different aspects or components of the GHS system on a varying set of timelines. Therefore, specific country or regional requirements need to be evaluated individually. This is especially true with regard to classification rules. For example, in the United States, crystalline silica (i.e., quartz) is considered a carcinogen while this is not the case in the EU. Similar variation exists for other compounds potentially contained in welding consumables and allied materials. As a consequence, the same product might have very different label and SDS requirements depending on where a product is to be supplied and shipped. This is something that manufacturers and distributors need to be aware of so that they can manage their business processes accordingly. In the Asia/Pacific region, there is a considerable degree of country-to-country variation when it comes to GHS adoption and classification and labeling requirements. In many ways, it is this nonharmonization with respect to these prescriptive classification and labeling requirements that may be the largest economic impact of GHS. Figure 2 shows an example of how a warning label might vary depending on whether the product is destined for the United States market or for the European market.
Figure 2

Figure 2

 GHS Hazard Classification Is Based on Intrinsic Properties of Substances As stated previously, classification is the foundation for implementing GHS and providing SDS and product labeling that meet the new requirements. According to the written GHS classification rules, stated in the GHS Purple Book, Section 1.3.2.2.1: “Only the intrinsic hazardous properties of substances and mixtures are to be considered.” This is important when considering the classification of solid-state, solid form welding consumables as they do not pose an intrinsic hazard, and it is not until they are actually used in the workplace and undergo their intended transformation during the welding process that they present any potential risks. For this reason, it is correct to consider them as “Not Classified” according to GHS. Of course, this statement does not mean that they pose no physical hazard or health risks when they are used in the welding process. For this reason, the welding industry must continue its long-standing practice of providing exceptional product warning and safe use information on packaging and in SDSs as it relates to the potential physical hazards and health risks that might be encountered when conducting welding or one of its allied processes. Such information is required in the GHS SDS in Sections 2, 8, and 11 where information on the hazards arising out of the conditions of use must be provided. These would include things like the constituents of health significance in fume, gases produced during product use, as well as the physical hazards that are created such as radiation from the arc. General hazards such as electrical and fire should be included in applicable sections of the SDS. The Not Classified determination in accordance with the GHS guidelines is the most appropriate in terms of providing the most accurate information to end users. If solid welding electrodes were to be classified based on their standard composition, hazard outputs could be confusing and/or misleading. For example, some shielded metal arc welding (SMAW) manual electrodes have crystalline silica in their base composition, but the material is bound in a solid extruded silicate matrix. In addition, when welding takes place, there is no subsequent exposure potential with respect to crystalline silica. It is predominantly complexed with metallic elements in the arc environment, and in any event, certainly does not survive the arc in crystalline form. However, if we classify based on standard composition, then much of the hazard classification and resulting warning outputs would be derived based upon crystalline silica content even though there is absolutely no exposure potential to these compounds during use or otherwise. Furthermore, there are also compounds and constituents present in the welding fume plume that may not exist in the base standard composition at all. Trying to conduct GHS classification based on the byproducts of consumable product decomposition or the welding process itself would get even messier. The degree to which some byproducts are formed is dependent upon the many conditions and process parameters selected by the user. Voltage settings, shielding gases, and the power supply wave characteristics of the process can all have a significant impact on the generation of potential contaminants. Perhaps the most significant is that the makeup of airborne welding byproducts can be heavily influenced by the particular substrate metal, base metal coatings present, and other aspects of the user’s unique application. Product diameter selection should also be considered as composition may vary by product diameter — and so this adds still another variable not necessarily controlled by the manufacture/supplier. Finally, obtaining complete decomposition chemistry for a wide range of conceivable user-controlled parameters would be extremely resource intensive and, in most cases, simply not feasible. GHS and OSHA Got It Right It seems as if the drafters of The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) did get it right when they specified that classification should be accomplished based upon the intrinsic hazards of a chemical substance or mixture. The fact that OSHA adopted these GHS guidelines without any appreciable modification also demon-strates its solid commitment to the GHS process and trust in the soundness of its foundational principles. The welding industry as a whole should support having a hazard communication process that provides all users with the most accurate hazard information possible. It will no doubt continue its past practices with respect to providing detailed hazard and risk information that ensures users have what they need in order to take the steps necessary to adequately protect themselves or their employees. While an additional investment of resources may be required on the front end by manufacturers and suppliers, a common system such as GHS, when used as designed, may ultimately help to do this most directly and consistently. Perhaps the GHS vision of a hazard communication process, fully harmonized on a global scale, can be one day realized.

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